Curing Kinetics of an Eutectic Aromatic Amine/ Epoxy ResinE44 by Nonisothermal DSC Method
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    Abstract:

    The curing reaction kinetics of an eutectic aromatic amine/ epoxy resin E44 system is investigated by
    nonisothermal DSC method. The kinetic parameters of this system are calculated by Kissinger, Ozawa and Crane equations:
    the apparent activation energy E =49. 2 kJ/ mol(by Kissinger and Ozawa methods), the reaction order n =
    0. 95(by Crane equation), the frequent factor A =2. 60×105 s-1(by Kissinger method). The kinetic model of the curing
    process based on n order reaction equation is established, which is used for modeling the curing reaction characteristics.
    The curing conditions are defined as follow: 50℃ /2 h, 140℃ /2 h, post-curing 200℃ /2 h. The curing behavior
    of the system is hardly affected by the change in the amount of the filler boron carbide (B4C) added into the
    eutectic aromatic amine/ epoxy resin E44 system.

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  • Online: November 28,2016
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