Abstract:A series of polyaluminosilazanes (PASZ) precursors were prepared by thermal polymerization with different proportion of polysilazanes liquid oligomers and aluminum acetylacetone [0.1%~1%(w)] as raw materials. The continuous SiAlCN(O) fibers were obtained via the melt spinning, air pre-oxidation treatment and high temperature cracking of PASZ. The PASZ and SiAlCN(O) fibers were characterized by FT-IR, GPC, SEM, XRD and metallographic microscopy. The results show that the mass average molecular weight of PASZ is from 7 191 to 11 275 g/mol, and prepared PASZ with 0.2% aluminum acetylacetone mass fraction shows shear thinning and excellent spinning property in molten state which could be continuously prepared up to 3 km. The SiAlCN(O) fiber is amorphous aluminum-containing silicon nitride fiber and the diameter of the fiber is about 20 to 70 μm, and the fiber surface is smooth, without obvious defects such as cracks and grooves.