异氰酸酯硅烷处理石英布/ PSA 树脂复合材料的影响
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华东理工大学材料科学与工程学院,

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TB332

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Effects of Isocyanate Coupling-Agent-Modification on Properites ofQF/ PSA Resin Composite
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    摘要:

    设计并选用一种分子结构中带有异氰酸酯基的硅烷偶联剂对石英布进行了表面处理,对比了石英
    纤维改性对含硅芳炔树脂复合材料部分力学、介电及耐热性能等的影响。结果表明:偶联剂处理石英纤维后,偶
    联剂与石英纤维表面发生化学键合,明显改善石英纤维与含硅芳炔树脂的界面粘接,复合材料的层间剪切强度比
    未处理的提高了24.7%,弯曲强度提升了12.4%,偶联剂的加入不会降低复合材料的Tg 和介电性能。

    Abstract:

    A silane coupling agent containing isocyanate was designed and employed to modify the interface of
    quartz fiber reinforced silicon containing arylacetylene( PSA) composite. The flexural properties, dielectric properties,
    heat-resistant properties and mechanical properties of GF/ PSA composite were compared. The results showed
    that, the interfacial adhesion performances between the fibers and the resin are improved by the chemical bonding between
    the coupling agent and the active groups on fibers surfaces. The interlaminar shear strength of the treated quartz
    fiber-PSA composite has been greatly improved by 24. 7% compared with those untreated. The results revealed that
    the flexural strength of composite increased 12. 4% after modified. The treating process on quartz fiber by IPTS had
    ignored effect on the dielectric properties of composite, and the insulating properties of composite are still excellent.
    No glass transition happened under the tested conditions, which meant the addition of IPTS wouldn’ t influence the
    heat-resistant of composite.

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扈艳红 梁秀华 杜 磊.异氰酸酯硅烷处理石英布/ PSA 树脂复合材料的影响[J].宇航材料工艺,2014,44(1).

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  • 在线发布日期: 2016-11-28
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