高密度PMI 泡沫塑料的制备、结构与性能研究
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西北工业大学理学院应用化学系

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Preparation, Structure and Properties of High Density PMI Foam
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    摘要:

    以丙烯腈、甲基丙烯酸为主单体制备AN/ MAA 型高密度PMI 泡沫塑料,探讨了发泡剂用量、发泡
    温度和发泡时间对PMI 泡沫塑料密度的影响规律,研究了高密度PMI 泡沫塑料的微观结构、力学性能和10
    GHz 的高频介电性能。结果表明,调控发泡剂用量为1 ~5 phr、发泡温度170 ~180℃、发泡时间40 min,可制备
    出密度为150 ~450 kg/ m3 的高密度PMI 泡沫塑料,随着其密度的增大,泡棱变粗、泡壁变厚、泡孔平均孔径变
    小;其拉伸、压缩强度显著增加,并与理论计算值基本一致;高频介电常数和介电损耗呈近线性规律增大。

    Abstract:

    High density Polymethacrylimide ( PMI) foam was prepared by using methacrylic acid( MAA) and
    acrylonitrile(AN) as the main monomers. The influence of the flowing agent dosage, foaming temperature and foaming
    time on the density of PMI foam was discussed. The microstructure, mechanical performance and dielectric electrical
    properties at 10 GHz of the high-density PMI foam were studied. The results indicate that high-density PMI foam
    with the density of 150 to 450 kg/ m3 can be obtained by foaming 40 min at 170 to 180℃ with 1 to 5 phr flowing agent.
    The bubble edges and bubble walls of the high-density PMI foam gradually thickened with the increase of the
    foam density, following the decrease of the average cellular diameter. Meanwhile, the mechanical properties including
    compression strength, tensile strength was improved gradually, which was closen to the theoretically calculated values,
    and the dielectric constant and dielectric loss increased linearly at the same time.

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引用本文

张 乐.高密度PMI 泡沫塑料的制备、结构与性能研究[J].宇航材料工艺,2012,42(6).

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  • 在线发布日期: 2016-11-28
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