The processing,heat-resistance and mechanical properties of novel modified cyanate ester ware evaluated in this article. The dielectric property and mechanical properties of cyanate ester matrix composite materials were also studied. The results showed that the cyanate ester adapted to madding prepreg by hot-melt methods because of its good process. All of the cyanate ester and composite materials had nice mechanical properties and could be used under 180℃. The composite materials are suitable for use as for high performance microwave-transparence materials and high frequency circuit boards.