玄武岩纤维/ 酚醛树脂复合材料界面结合机理
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北京林业大学材料科学与技术学院

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Bonding Mechanism of Basalt Fiber Reinforced Phenolic Resin
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    摘要:

    分别用浓度为0.8wt% 和1.0wt%的KH550 硅烷偶联剂处理玄武岩纤维布,并制作成玄武岩纤维增
    强酚醛树脂(PF-BFRP)。经过力学检测和SEM 的分析结果表明:0. 8wt%组复合材料力学性能略高于1. 0%组,
    且该组纤维表面的树脂附着层较厚且分布均匀,单根纤维表面的树脂附着量较多。根据FTIR 结果的分析,推测
    出复合界面新形成的化学键为C—N—C 和C—O—Si。树脂中苯酚与纤维表面的氨基、硅醇基分别形成了C—
    N—C 键、C—O—Si 键。XPS 测试证实了0.8wt%组C—O—Si 键的峰面积比大于1.0wt%组,说明0.8wt%组复合
    材料具有更好的界面性能。

    Abstract:

    Basalt fiber was treated with concentration of 0. 8wt% and 1. 0wt% of KH550 silane coupling agent
    respectively, and basalt fiber鄄reinforced phenolic resin (basalt fiber reinforced phenolic resin, BFR鄄phenolic) was
    made. After mechanical testing and SEM analysis, we found that the mechanical properties of 0. 8wt% group was
    slightly higher than 1. 0wt% group. also the resin layer of 0. 8wt% group is thick and evenly distributed,the resin atta鄄
    ched to the surface of a single fiber is more than others; FTIR test had determined the formation of the new chemical
    bonds may be C—N—C, C—O—Si; formation of C—N—C bond between phenol and amino on the composite inter鄄
    face,and formation of C—O—Si bond between phenol and silanol. XPS tests confirmed that the 0郾8wt% group
    formed more C—O—Si bonds,which made it better composite interface.

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张莉.玄武岩纤维/ 酚醛树脂复合材料界面结合机理[J].宇航材料工艺,2012,42(3).

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  • 在线发布日期: 2016-11-28
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