聚酰胺改性酚醛树脂及泡沫性能
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航天材料及工艺研究所,先进功能复合材料技术重点实验室

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Polyamide Modified Phenolic Resin and Phenolic Foam Properties
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    摘要:

    为了改善酚醛泡沫的韧性,采用聚酰胺对酚醛树脂进行了改性,并通过化学发泡法制备了不同含量
    聚酰胺改性酚醛泡沫,借助DSC 曲线、凝胶化时间、弯曲强度、SEM 照片等表征方法研究了聚酰胺对酚醛树脂及泡
    沫性能的影响。结果表明:聚酰胺与酚醛树脂发生了共固化反应;酚醛树脂的反应活性随着聚酰胺含量的增加逐
    渐降低;加入的聚酰胺有效的改善了酚醛泡沫的韧性;酚醛泡沫弯曲强度随着聚酰胺含量的增加呈现先增加后减
    小的趋势,当聚酰胺含量为10wt%时,弯曲强度达到最大,比未改性的提高了约81%;酚醛泡沫SEM 照片显示少
    量聚酰胺可以改善泡沫的泡孔结构,当聚酰胺加入量为10wt%时,酚醛泡沫泡孔结构最好,泡孔大小均匀,平均直
    径约为400 滋m。

    Abstract:

    The phenolic resin was modified by polyamide for improving the toughness of phenolic foam,and was
    foamed by chemical method. The effect of polyamide on the properties of phenolic resin and foam was studied with the
    analytical methods including DSC, gel鄄time,bending strength,and SEM. The results showed that the co鄄curing between
    polyamide and phenolic resin happened,the reactivity of phenolic resin decreased with the increasing of polyamide,the
    polyamide improved the toughness of phenolic foam effectively,the bending strength of phenolic foam presented the trend
    of up first and down second with the increasing of polyamide,and attained the most enhancing about 81% than the un鄄
    modified when the content is 10wt%,the bubble structure of phenolic foam is improved from the SEM images by adding
    a little of polyamide,when adding 10wt% it is best and the bubble size is symmetrical in which the average diameter is
    about 400 滋m.

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引用本文

缪长礼.聚酰胺改性酚醛树脂及泡沫性能[J].宇航材料工艺,2012,42(2).

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  • 在线发布日期: 2016-11-28
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