不同T300 级碳纤维轴棒法C/ C 复合材料的导热性能
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西安航天复合材料研究所,西安 710025

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Thermal Conductance of Axial Carbon Rods C/ C Composites WovenWith Different T300 Carbon Fiber
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    摘要:

    选取两种国产T300 级PAN 基碳纤维,轴棒法制备4D 预制体,以高温煤沥青为前驱体,采用液相
    浸渍-炭化以及石墨化相结合的技术制备C/ C 复合材料( 密度逸1. 95 g/ cm3 ),研究了C/ C 复合材料从室温
    (RT)到800益的热导率及其影响因素。研究表明,在实验温度范围内C/ C 复合材料的热导率随温度升高而降
    低,由于原材料自身特性和预制体编织结构具有方向性,使C/ C 复合材料的导热性能表现出各向异性,径向热
    导率明显高于轴向;密度高、开孔率小、石墨化程度高的C/ C 复合材料由于晶粒间连通状态好,微晶结构趋于
    完整,材料的热导率增大;以低压热处理为最终处理工艺的C/ C 复合材料热导率略有提高;采用国产T300 级
    与东丽T300 碳纤维制备的C/ C 复合材料的热导率相当。

    Abstract:

    By taking axial carbon rods 4D preform woven with two kinds of T300 grade PAN based carbon fiber
    made in China as reinforcement and high temperature coaltar pitch as matrix precursor, the C/ C composites with a
    density up to 1. 95 g/ cm3 were prepared by using combined impregnationcarbonization and graphitization techniques.
    Thermal conductivity of the C/ C composites from RT to 800益and the influencing factors were discussed. The results
    show that thermal conductance of the C/ C composites is decreased with increasing of the temperature under the experimental condition. Because of the own features of raw materials and the directivity of preform, the thermal conductivity
    of the C/ C composites along radial direction is higher than that of axial direction. C/ C composites with higher density, lower porosity and higher graphitization degree have higher thermal conductivity due to their excellent connectivity
    between crystal particles and gradually perfected crystal microstructure. The thermal conductivity of the C/ C composites with low pressure heat treatment as its final process is higher than that after high pressure carbonization. The thermal conductivity of C/ C composites prepared by T300 carbon fibers made in China is similar to that of the C/ C composites prepared by Toray T300 carbon fibers.

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冯阳阳 崔红 李瑞珍 吴书峰.不同T300 级碳纤维轴棒法C/ C 复合材料的导热性能[J].宇航材料工艺,2011,41(2).

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  • 在线发布日期: 2016-11-28
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