环氧类韧性耐烧蚀防热涂层的研制与表征
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航天材料及工艺研究所,北京 100076

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Development and Evaluation of Epoxy BasedTough Ablation Resistant Coating
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    摘要:

    针对现有环氧类防热涂层韧性差、不耐烧蚀的缺点,设计了一种环氧类防热涂层———TR-48。测
    试了其基本性能及3-5 个批次的典型性能,并与国外现有涂层进行了比较。结果证明:TR-48 具有韧性好、强
    度高、耐烧蚀等特点;其中拉伸强度为8. 7-11. 2 MPa,伸长率为6. 8% -12. 2%,TG 分析800益残碳率为51%,
    800益马弗炉烧蚀5 min 残碳率为38% -47%。利用SEM、DSC 表征了涂层的烧蚀过程,发现600-800益存在烧
    结反应。利用液氧/ 煤油发动机和电弧风洞考核试验考核了涂层在高温、高速气流环境下的表现,结果表明该
    涂层具有较好的抗冲刷及防热性能。

    Abstract:

    A novel epoxy based coating designated as TR-48 is developed in house at Aerospace Research Insti
    tute of Materials & Processing Technology. This material is composed of toughened epoxy binder for durable performance and is filled with special carbonate agent for improvement of ablation resistance. The TR-48 coating is evaluated
    by mechanical property testing,thermal physics property testing,ablation testing,as well as batch stable testing. The
    tensile strength is 8. 7 to 11. 2 MPa,elongation rate is 6. 8% to 12. 2%,mass retained in TG analysis at 800益is
    51%,mass retained after 800益,5 min static ablation is 38% to 47%. It is also found that sinter reaction during 600
    to 800益is the main reason which makes ablation resistance improved. Then the TR-48 is qualified by thermal testing
    in a wind tunnel or under an oxygen kerosene engine to simulate the hypersonic aerodynamic heating and exhaust erosion. This material is characterized by excellent thermal protection performance and good ablation resistance.

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左瑞霖 李晨光 王慧 孙伟华 任英.环氧类韧性耐烧蚀防热涂层的研制与表征[J].宇航材料工艺,2011,41(2).

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  • 在线发布日期: 2016-11-28
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