SiC 抗氧化机制电弧加热试验
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中国航天空气动力技术研究院


Oxidation Resistance Mechanism of SiC in Arc Heater
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    摘要:

    介绍了在电弧加热器上进行的SiC 的抗氧化机制研究试验,根据SiC 的主动、被动氧化机制,调
    试出相应试验条件并进行了模型试验。结果表明,SiC 在一定的氧分压环境中,表面温度低于转捩温度时,会
    在表面形成SiO2薄膜,阻止氧向防热层内部扩散,降低了碳同氧的反应程度,阻止了基体碳的烧蚀;当表面温
    度高于转捩温度时材料发生主动氧化,材料表面发生烧蚀。

    Abstract:

    The experiment of oxidation resistance mechanism for silicon carbide in arc heater is introduced. Test
    conditions were confirmed according to active and passive oxidation mechanism of the SiC composite material. The results indicated that the silicon dioxide (SiO2) film appeared on the surface of silicon carbide when the surface temperature is less than the transition temperature;the film prevented the ablation of the materials because that decreased the reaction between oxygen and carbon materials. On the other hand,the silicon carbide surface ablated when the surface temperature is higher than the transition temperature.

    参考文献
    [1] Fertig M,Fruhauf H H,Auweter Kurtz M. Modlling of
    reactive processes at SiC surfaces in rarefied nonequilibrium. Air flows[R]. AIAA 2002-3102
    [2] Hald H,Ullmann T. Reentry flight and ground testing experience with hot structures of C/ C-SiC material[R]. AIAA 2003-1667
    [3] Marianne J H. Determination of the active to passive transition in the oxidation of silicon carbide in standard and microwave excited Air[J]. Journal of the European Ceramic Society,
    1996,16:55-62
    [4] Frank S M,Jochen Marschall. Thermochemical ablation model for TPS materials with multiple surface constituents[R].AIAA,94-2042
    [5] 陈思员,姜贵庆,俞继军,等. 碳化硅材料被动氧化机理及转捩温度分析[J]. 宇航材料工艺,2009,39(3):21-24
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欧东斌 陈连忠 张敏莉 陈思员. SiC 抗氧化机制电弧加热试验[J].宇航材料工艺,2010,40(3).

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  • 在线发布日期: 2016-11-28
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