N2流量对CrAlYN涂层结构、力学及热稳定性的影响研究
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1.兰州城市学院培黎石油工程学院,兰州 730070;2.中国科学院兰州化学物理研究所固体润滑国家重点实验室,兰州 730000;3.兰州城市学院培黎机械工程学院,兰州 730000

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TG174.4

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甘肃省教育厅高校教师创新基金项目(2024B-146); 甘肃省科技计划资助(24JRRA529);国家自然科学基金(No.52265023)


Effect of N2 Flow Rate on the Structure, Mechanics and Thermal Stability of CrAlYN Coating
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1.Bailie School of Petroleum Engineering, Lanzhou City University, Lanzhou 730070;2.National Key Laboratory of Solid Lubrication, Lanzhou Institute of Chemical Physics, Chinese Academy of Sciences, Lanzhou 730000;3.School of Bailie Mechanical Engineering, Lanzhou City University, Lanzhou 730070

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    摘要:

    N2流量对CrAlYN涂层的结构和性能影响较大,因此,本文系统研究了N2流量对CrAlYN涂层结构、力学及热稳定性的影响。结果表明,当N2流量从23 mL/min增大到38 mL/min时,涂层中氮原子含量从26.45 at.%增加到52.20 at.%。当N2流量为33 mL/min时,涂层中氮含量为49.00 at.%,元素组成符合化学计量比,涂层具有最高的硬度和抗塑性变形能力。XRD和TEM等分析表明,低N2流量下制备的涂层具有纳米晶结构,硬度较低。高N2流量下制备的涂层呈现柱状晶结构,氮原子的注入效应使涂层张应力增大,硬度降低。在33 mL/min的N2流量下制备的涂层晶粒较小,结构致密,硬度达到24.6 GPa,1 000 ℃退火后涂层氧化轻微,硬度为18.4 GPa,高于其他N2流量下制备的涂层,表明该CrAlYN涂层具有最好的综合性能。

    Abstract:

    The flow rate of N2 had a significant impact on the structure and performance of CrAlYN coatings, so this study systematically investigated the influence of N2 flow rate on the structure, mechanical properties, and thermal stability of CrAlYN coatings. The results show that as the N2 flow rate increases from 23 mL/min to 38 mL/min, the nitrogen content in the coating increases from 26.45 at.% to 52.20 at.%. When the N2 flow rate is 33 mL/min, the nitrogen content in the coating is 49.00 at.%, and the elemental composition conforms to the stoichiometric ratio. The coating has the highest hardness and resistance to plastic deformation. XRD and TEM analyses show that coatings with low N2 flow rate has a nanocrystalline structure and lower hardness. The coatings with high N2 flow rate has a columnar crystal structure, and the injection of nitrogen atoms increases the compressive stress of the coating and reduces its hardness. The coating with a N2 flow rate of 33 mL/min has smaller grains and a dense structure, with a hardness of 24.6 GPa. After annealing at 1 000 °C, the coating shows slight oxidation and a hardness of 18.4 GPa, which is higher than that of coatings with other N2 flow rates, indicating that this CrAlYN coating has the best overall performance.

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付英英,吉利,王翔,董向成,国洪建. N2流量对CrAlYN涂层结构、力学及热稳定性的影响研究[J].宇航材料工艺,2024,54(4):87-92.

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历史
  • 收稿日期:2023-08-28
  • 最后修改日期:2024-08-14
  • 录用日期:2023-11-16
  • 在线发布日期: 2024-09-03
  • 出版日期: 2024-08-31