工艺参数对MB8镁合金微弧氧化膜层结构和耐蚀性的影响
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1.湖南科技大学机电工程学院,湘潭 411201;2.广东科技学院机电工程学院,东莞 520823

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TG174.4

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广东省青年创新人才项目(2022KQNCX116);东莞市科技特派员项目(20231800500602);教科创教学相长项目化团队(GKJXXZ2023026);大学生创新创业训练计划项目(202213719001、202313719003);广东科技学院节能减排创新团队(GKY-2022CQTD-1)


Effect of Process Parameters on the Structure and Corrosion Resistance of Micro Arc Oxidation Film Layer of MB8 Magnesium Alloy
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1.School of Mechanical and Electrical Engineering, Hunan University of Science and Technology,Xiangtan 411201;2.School of Mechanical and Electrical Engineering, Guangdong University of Science and Technology,Dongguan 523083

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    摘要:

    为了提高镁合金的耐腐蚀性,通过微弧氧化技术在MB8镁合金表面制备一层微弧氧化膜层。采用X射线衍射仪(XRD)、扫描电镜(SEM)、电化学工作站、膜层测厚仪等设备对微弧氧化膜层性能进行表征。基于正交试验方法,研究占空比、频率和时间三个因素对微弧氧化膜层的厚度、表面孔隙率以及腐蚀电流密度的影响规律。研究表明,与MB8镁合金相比,微弧氧化膜层的腐蚀电流密度下降两个数量级,耐腐蚀性得到显著提升。影响膜层厚度、孔隙率和耐腐蚀性指标的主次顺序依次为占空比、频率、氧化时间。频率相同时,随着占空比的增加,膜层表面孔隙率均呈先增后减。占空比为50%、频率为1.8 kHz、氧化时间为15 min工艺下制备的膜层性能最佳,膜层厚度为18.6 μm,孔隙率为6.21%,腐蚀电流密度为2.56×10-6 A/cm2

    Abstract:

    In order to enhance the corrosion resistance of magnesium alloys, a micro arc oxidation coating was prepared on the surface of MB8 magnesium alloy using micro arc oxidation technology. The performance of the micro arc oxidation coating was characterized using X-ray diffraction (XRD), scanning electron microscopy (SEM), electrochemical workstation, and coating thickness measurement. Based on an orthogonal experimental method, the influences of duty cycle, frequency, and oxidation time on the thickness, surface porosity, and corrosion current density of the micro arc oxidation coating were investigated. The results reveal that, compared to MB8 magnesium alloy, the corrosion current density of the micro arc oxidation coating decreased by two orders of magnitude, indicating a significant improvement in corrosion resistance. The order of importance on the thickness, porosity, and corrosion resistance of the coating was found to be duty cycle, frequency, and oxidation time, respectively. At a fixed frequency, the surface porosity of the coating initially increases and then decreases as the duty cycle increases. The optimal performance of the membrane is achieved under conditions of a 50 % duty cycle, a frequency of 1.8 kHz, and an oxidation time of 15 minutes, resulting in a coating thickness of 18.6 μm, a porosity of 6.21%, and a corrosion current density of 2.56×10-6 A/cm2.

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姜炳春,文泽军,侯杰,黄鑫婷,卢立伟.工艺参数对MB8镁合金微弧氧化膜层结构和耐蚀性的影响[J].宇航材料工艺,2025,55(6):68-75.

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  • 收稿日期:2023-07-24
  • 最后修改日期:2024-10-20
  • 录用日期:2024-10-29
  • 在线发布日期: 2025-12-29
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