氧化石墨烯/银/聚苯胺复合材料的制备及其在导电橡胶中的性能研究
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北京遥感设备研究所,北京 100854

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TQ333.93

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Preparation of Graphene Oxide/Ag/Polyaniline Composite and Its Performance Porperties in Conductive Rubber
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Beijing Institute of Remote Sensing Equipment,Beijing 100854

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    摘要:

    为降低导电橡胶制造成本,提升工程应用价值,采用原位法合成了氧化石墨烯/银/聚苯胺(GAP)复合材料,并制备了GAP增强导电橡胶。SEM等表征结果显示,Ag+离子和苯胺单体以氧化石墨烯为模板,原位生长成纳米银颗粒和枝状聚苯胺,形成GAP复合材料。GAP粉体能够有效分散至硅橡胶基体中获得增强橡胶材料。当添加量为100 phr时,硅橡胶拉伸强度达到4.67 MPa,断裂伸长率为430%,拉伸模量为0.76 MPa,体积电阻率则达到8.1 mΩ·cm,与银粉增强硅橡胶相当(对比试验分别为4.89 MPa、422%、0.72 MPa和5.4 mΩcm)。GAP增强硅橡胶邵尔A硬度为64,相比银粉增强硅橡胶(76)降低了15.8%,具有较高的工程应用价值,制造成本也有望下降。

    Abstract:

    To reduce the manufacturing cost of conductive rubber and enhance its engineering applicability,a graphene oxide/silver/polyaniline(GAP)composite was synthesized via an in situ route,and GAP-reinforced electrically conductive silicone rubber was prepared.Characterization by SEM shows that,using graphene oxide as a template,Ag⁺ ions and aniline monomers grew in situ into silver nanoparticles and dendritic polyaniline,forming the GAP composite.The GAP powder disperses effectively within the silicone-rubber matrix to yield a reinforced elastomer.At a loading of 100 phr,the silicone rubber exhibites a tensile strength of 4.67 MPa,an elongation at break of 430%,a tensile modulus of 0.76 MPa,and a volume resistivity of 8.1 mΩ·cm,and comparable to Ag-powder-filled silicone rubber(control values:4.89 MPa,422%,0.72 MPa,and 5.4 mΩcm).The Shore A hardness of the GAP-reinforced silicone rubber is 64,a 15.8% reduction relative to the Ag-powder-filled counterpart(76).These results indicate high practical utility for engineering applications,with the prospect of reduced manufacturing costs.

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李嘉伟,贾海斌,刘迅,李晨东.氧化石墨烯/银/聚苯胺复合材料的制备及其在导电橡胶中的性能研究[J].宇航材料工艺,2025,55(5):74-80.

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  • 收稿日期:2023-06-27
  • 最后修改日期:2025-09-25
  • 录用日期:2023-10-30
  • 在线发布日期: 2025-10-30
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