粉末特性对W-Ti[w(Ti)=10%]合金致密度和组织的影响
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航天材料及工艺研究所,北京 100076

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TG14

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Effect of Powder Characteristics on Density and Microstructure of W-Ti[w(Ti)=10%] Alloy
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Aerospace Research Institute of Materials & Processing Technology,Beijing 100076

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    摘要:

    制备了W-Ti[w(Ti)=10%]合金,研究了粉末纯度、W粉粒度对W-Ti[w(Ti)=10%]合金密度、组织的影响。发现粉末纯度越高,W-Ti[w(Ti)=10%]合金的致密度越高,富Ti相占比越低。3N纯度的W-Ti[w(Ti)=10%]合金内部会留存纯Ti,富Ti相占比为31.28%,4N和4N5纯度的W-Ti[w(Ti)=10%]合金不存在纯Ti,富Ti相占比分别为28.41%、21.67%。W粉粒度的影响体现在两个方面:W粉粒度越大,与Ti粉的混合效果越好,越有利于扩散;但比表面积越小,越不利于扩散。随着W粉粒度增大,W-Ti[w(Ti)=10%]合金的富Ti相含量先降低后升高。本实验中,当W粉粒度为4~5 μm,Ti粉粒度为44 μm时,W-Ti[w(Ti)=10%]合金的组织性能最优,富Ti相占比为28.79%。

    Abstract:

    W-Ti[w(Ti)=10%] alloy was prepared, and the influence of powder purity and W powder size on the density and microstructure of W-Ti[w(Ti)=10%] alloy was studied. It is found that the higher the purity of powder, the higher the density of W-Ti[w(Ti)=10%] alloy, and the lower the Ti rich phase proportion. The W-Ti[w(Ti)=10%] alloy with 3N purity will retain pure Ti, and the proportion of Ti-rich phase is 31.28%. The W-Ti[w(Ti)=10%] alloy with 4N and 4N5 purity does not have pure Ti, and the proportion of Ti-rich phase is 28.41% and 21.67%, respectively. The influence of W powder particle size is reflected in two aspects: the larger the W powder particle size, the better the mixing effect with Ti powder, the more conducive to diffusion; but the smaller the specific surface area, the less conducive to diffusion. With the increase of W particle size, the Ti-rich phase content of W-Ti[w(Ti)=10%] alloy decreases first and then increases. In this experiment, when the particle size of W powder is 4~5 μm and the particle size of Ti powder is 44 μm, the microstructure properties of W-Ti[w(Ti)=10%] alloy are the best, and the proportion of Ti-rich phase is 28.79%.

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杨亚飞,姚草根,吕宏军,谢飞,孟烁.粉末特性对W-Ti[w(Ti)=10%]合金致密度和组织的影响[J].宇航材料工艺,2024,54(5):31-39.

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  • 收稿日期:2023-06-13
  • 最后修改日期:2024-11-28
  • 录用日期:2023-10-25
  • 在线发布日期: 2024-12-03
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