桥联型柔性硅基气凝胶的制备及性能
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1.天津工业大学纺织科学与工程学院,天津 300387;2.航天材料及工艺研究所,北京 100076

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O648.18

基金项目:

国家自然科学基金(No.52003071);北京市科技新星计划(Z211100002121090)


Preparation and Properties of Bridged Flexible Silicon Aerogel
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1.School of Textile Science and Engineering,Tiangong University,Tianjin 300387;2.Aerospace Research Institute of Materials Processing Technology,Beijing 100076

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    摘要:

    硅基气凝胶是一种具有优异性能的材料,但其力学性能差,干燥方式繁琐,严重限制了其实际应用。对此,本文以对苯二甲醛和3-氨基丙基三甲氧基硅烷为前驱体,甲基三甲氧基硅烷和二甲基二甲氧基硅烷为共前驱体,采用溶胶-凝胶法和常压干燥法制备了新型桥联型二氧化硅气凝胶,探究了n(H2O/Si)对气凝胶性能的影响,对制备的桥联型气凝胶的密度、收缩性、疏水性、力学性能和热性能进行了详细的研究。结果表明,当n(H2O/Si)为4时所制备的气凝胶具有较低密度(82 mg/cm3)和热导率[29 mW/(m·K)]、较高疏水性(接触角150°)和优异的柔韧性(E=40 kPa),在50%应变下,经过100次压缩循环后,应力仅降低10%。热重分析表明,在380 ℃的氮气气氛内,质量损失小于5%,具有优异的热稳定性。

    Abstract:

    Silica-based aerogels were materials with outstanding properties,but their poor mechanical performance and cumbersome drying methods severely limited their practical applications.Here,using terephthalaldehyde and 3-aminopropyltrimethoxysilane as precursors,combined with methyltrimethoxysilane and dimethyldimethoxysilane as co-precursors,a novel bridged silica aerogel via a sol-gel process and atomspheric pressure drying method was produced.The effect of the molar ratio n(H2O/Si) on aerogel performance was investigated and the density,shrinkage,hydrophobicity,mechanical properties,and thermal characteristics of the prepared crosslinked aerogels were detailed.The results show that at n(H2O/Si)=4,the aerogel exhibits low density(82 mg/cm³) and thermal conductivity [29 mW/(m·K)],high hydrophobicity(contact angle150°),and excellent flexibility(E=40 kPa);under 50% compressive strain,the stress decreases by only 10% after 100 loading-unloading cycles.Thermogravimetric analysis indicates superior thermal stability,with mass loss 5% at 380 ℃ under nitrogen.

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李红晨,郑振荣,罗丽娟,李好帅,李纪康.桥联型柔性硅基气凝胶的制备及性能[J].宇航材料工艺,2025,55(5):68-73.

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  • 收稿日期:2023-06-01
  • 最后修改日期:2025-09-30
  • 录用日期:2023-07-26
  • 在线发布日期: 2025-10-30
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