自控温复合材料的制备与性能
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作者单位:

1.华南理工大学化学与化工学院,广州 510641;2.上海卫星工程研究所,上海 200240;3.华南理工大学珠海现代产业创新研究院,珠海 519175

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TQ336.8

基金项目:

珠海市基础与应用基础课题基金(ZH22017003210078PWC);上海航天科技创新基金(SAST2022-047)


Preparation and Properties of Self-controlled Temperature Composites
Author:
Affiliation:

1.School of Chemistry and Chemical Engineering, South China University of Technology,Guangzhou 510641;2.Shanghai Institute of Satellite Engineering,Shanghai 200240;3.SCUT-Zhuhai Institute of Modern Industrial Innovation,Zhuhai 519175

Fund Project:

Zhuhai Fundamental and Applied Fundamental Topics Fund Project Grant

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    摘要:

    为解决航空领域现存在的热控系统质量重、体积大的问题,本文以室温硫化硅橡胶为基体,炭黑(CB)、碳纳米管(CNTs)和镍(Ni)为导电填料,并且添加一系列助剂,采用溶液共混法制备室温硫化硅橡胶基PTC材料,并对其进行阻-温性能测试和自控温性能测试,验证了复合材料的PTC效应及温控能力;并对材料的微观结构进行了分析,提出了交链-膨胀结构理论模型。结果表明,当CB/CNTs/Ni混合填充量为16 wt%时,复合材料的室温电阻率较低,为19.95 Ω·cm,PTC强度较高,为4.73,并且在经过300次冷热循环后,仍表现出较好的升温能力和控温能力。TG分析可以看出CB/Ni/CNTs的加入提高了硅橡胶的耐热性能;通过SEM分析可以看出,极大长径比的CNTs具有一定抑制CB团聚的作用;通过XRD分析可以得出导电填料在硅橡胶基质中分散较为均匀的结论。基于微观结构的分析,对内部导电网络通道和结构变化进行对比分析,构建了影响PTC效应的因素分析模型,为解决航空领域的热控系统减重问题提供了可行性参考。

    Abstract:

    In order to solve the problems of heavy weight and large volume of thermal control systems for the aerospace applications, in this study, a PTC (Positive Temperature Coefficient) material based on RT-vulcanized silicone rubber was synthesized via the solution blending method. The composite comprised RT-vulcanized silicone rubber as matrix, and carbon black (CB), carbon nanotubes (CNTs), and nickel (Ni) as conductive fillers. Additionally, various additives were incorporated into the composite. To evaluate the material''s performance, its resist-temperature characteristics and automatic temperature regulation capabilities were assessed, confirming its PTC effect and temperature control efficiency. Furthermore, the microstructure of the material was analyzed, leading to the proposal of a theoretical model for the cross-linking expansion structure. The results demonstrate that when the filling amount of CB/CNTs/Ni mixture is 16wt%, the room temperature resistivity of the composite material is significantly reduced to 19.95 Ω·cm, exhibiting a high PTC strength of 4.73. Additionally, after undergoing 300 cold and hot cycles, excellent heating and temperature control performance of the composite are preserved. Thermogravimetric (TG) analysis demonstrates that the incorporation of CB/Ni/CNTs significantly enhance the thermal stability of silicone rubber. Scanning electron microscopy (SEM) reveals that CNTs with a high aspect ratio exert a notable inhibitory effect on the agglomeration of carbon black (CB). X-ray diffraction (XRD) analysis indicates that the dispersion of conductive fillers within the silicone rubber matrix is relatively uniform. Based on the analysis of microstructure, the internal conductive network channels and structural changes are compared and analyzed, and an analytical model of factors affecting the PTC effect is constructed, which provides a feasible reference for solving the problem of weight reduction of the thermal control system in the field of aviation.

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引用本文

李静,张希,沈斌,李金环,段诗雨.自控温复合材料的制备与性能[J].宇航材料工艺,2025,55(2):51-58.

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  • 收稿日期:2022-10-14
  • 最后修改日期:2023-01-19
  • 录用日期:2023-02-24
  • 在线发布日期: 2025-05-12
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《宇航材料工艺》2025年青年编委招募启事

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