星载低真空逸气氰酸酯树脂的制备与性能
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上海卫星装备研究所,上海 200240

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V45

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上海市启明星培育(杨帆专项)基金(项目编号:22YF1446900)


Preparation and Properties of Spaceborne Low Vacuum Outgassing Cyanate Ester Resin
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Shanghai Institute of Spacecraft Equipment, Shanghai 200240

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    摘要:

    通过在氰酸酯树脂中添加不同低含量环氧树脂AG80和催化剂苄基二甲胺(BDMA),分析了低含量环氧树脂改性氰酸酯树脂的微观结构、固化热效应、真空逸气特性、力学性能、吸水率和热失重。实验结果表明,在催化剂BDMA的作用下,当环氧树脂AG80的质量分数为5%和8%时,可以有效促进氰酸酯的固化程度,减少未固化小分子数量,进而改善氰酸酯材料的真空逸气性能。其中BADCy-1的真空逸气性能和耐湿性能达到最优,总质量损失(TML)和可凝挥发物(CVCM)分别为0.41%和0.03%,吸水率降低15%。BADCy-2的力学性能达到最优,拉伸强度和弯曲强度改善效果显著,分别提高23%和20%。同时随着环氧树脂含量的增加,材料的耐热性能有所下降。

    Abstract:

    The cyanate ester resins were prepared by adding different low content epoxy AG80 and benzyl dimethylamine (BDMA). The microstructure, curing heat effect, vacuum outgassing properties, mechanical properties, water absorption and thermal weight loss of low content epoxy modified cyanate ester resin were analyzed. The experimental results show that AG80 epoxy resin with mass fraction of 5% and 8% can effectively promote the curing degree of cyanate ester, reduce the number of uncured small molecules, and improve the vacuum outgassing properties of cyanate ester resin under the action of catalyst BDMA. BADCy-1 has the best vacuum outgassing properties and moisture resistance, in which the total mass loss (TML) and collected volatile condensable material (CVCM) are 0.41% and 0.03%, respectively, and the water absorption is reduced by 15%. The mechanical properties of BADCy-2 are optimized, and the tensile strength and flexural strength are improved by 23% and 20%, respectively. At the same time, the heat resistance of the material decreases with the increase of epoxy resin content.

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曹洪涛,马海龙,程涛,夏振涛,孟凡苹.星载低真空逸气氰酸酯树脂的制备与性能[J].宇航材料工艺,2024,54(1):49-55.

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  • 收稿日期:2022-02-20
  • 最后修改日期:2024-02-07
  • 录用日期:2022-05-09
  • 在线发布日期: 2024-03-04
  • 出版日期: 2024-02-29
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