三种高强铝合金高温组织实时观察研究
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航天材料及工艺研究所,北京 100076

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TG444.2

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航材院钛合金型材应用研究项目(KZ82171509)


In-situ Observation of High Temperature Microstructure Evolution of Three Kinds of High-strength Aluminum Alloys
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Aerospace Research Institute of Materials & Processing Technology, Beijing 100076

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    摘要:

    2219、2A14、2195铝合金是航天领域常用的三种结构材料,特别是2195合金,因其密度低、比强度和比刚度高等优势在航天的应用越来越广泛。本文基于高温金相实时观测系统,在50 K/min加热速率下对强化态(固溶+时效)下的三种铝合金常温(约25 ℃)至软化温度(约600~660 ℃)下微观组织及相组成的变化过程进行了实时观察。结果表明:强化态下的三种铝合金均在高于其固相线的温度下发生了熔化,高温金相视场中的初始熔化位置位于圆形相(含有Al、Cu元素)附近,而块状相(含有Al、Cu、Fe等元素)则最后发生熔化。重新凝固后材料显微硬度降低50%左右,表明基体中的增强相减少;先析α相中Cu含量降低,大部分Cu元素均富集于晶界上形成接近共晶成分的网状富Cu相;未溶块状相熔点较高,重新凝固后被推移到晶界。对三种铝合金分析对比结果表明,2195合金固液温度区间最小,高温下形成的网状富Cu液膜最容易被拉开,因此该材料热裂纹敏感性最大。

    Abstract:

    2219, 2A14 and 2195 alloys were three kinds of structural materials for aerospace application. Particularly, 2195 alloy was more and more widely used in aerospace industry because of its low density, high specific strength and rigidity and etc. By using the in-situ observation system of high temperature metallography, the microstructure evolution and phase transformation of three kinds of aluminum alloys in strengthened condition from room temperature (about 25 ℃) to zero strength temperature (about 600~660 ℃) at a heating rate of 50K/min was investigated. The results show that three kinds of aluminum alloys melt at a temperature higher than the solidus curve, the first melting position lies around the spherical phase (containing Al, Cu), and that the massive phases (containing Al, Cu, Fe, etc) melt at last. After the cycled-water solidification process, the micro-hardness of the re-solidified materials decreases by about 50%, indicating that the strengthening phase in the matrix decreases. The Cu content of primary α phase decreases, and most of the Cu element remains at the grain boundaries, forming net-like Cu-rich phase whose composition is close to eutectic composition, and a few massive phases that do not dissolve completely are forced to the grain boundaries. As a result of the comparison of three alloys, the conclusion is drawn that 2195 alloy, which has the smallest solid-liquid temperature interval, is susceptible to thermal cracks since the Cu-rich liquid films are easily torn apart by thermal stress.

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袁建宇,王影,逄锦程,谢国君,卢鹉.三种高强铝合金高温组织实时观察研究[J].宇航材料工艺,2023,53(1):85-93.

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  • 收稿日期:2021-10-13
  • 最后修改日期:2023-02-16
  • 录用日期:2022-04-12
  • 在线发布日期: 2023-03-29
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