国产M55J级碳纤维与两种典型树脂界面性能研究
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1.上海复合材料科技有限公司,上海 201112;2.上海航天树脂基复合材料工程技术研究中心,上海 201112

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TB332

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The Interfacial Properties of Domestic M55J Carbon Fiber and Two Typical Resins
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1.Shanghai Composites Science and Technology Limited Company, Shanghai 201112;2.Shanghai Engineering Research Center of Aerospace Resin Based Composite, Shanghai 201112

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    摘要:

    为了夯实国产M55J级碳纤维在航天构件中的应用基础,重点研究了国产M55J级碳纤维与航天环氧和氰酸酯树脂的界面性能,并与进口M55J碳纤维进行对比。采用扫描电子显微镜、原子力显微镜对碳纤维的微观形貌进行表征,通过接触角测量、红外光谱分析和微脱粘测试对碳纤维与航天树脂的粘附功、浸润性、化学反应特性和界面剪切强度进行测定。结果显示,国产M55J级碳纤维表面存在大量沟槽,上浆剂形成少量突起;国产M55J级碳纤维与两种树脂的浸润性优于M55J碳纤维与树脂浸润性,国产M55J级碳纤维与两种航天树脂的粘附功分别为55.76和48.61 mN/m,均高于进口碳纤维的粘附功;国产M55J级碳纤维上浆剂与两种航天树脂经高温固化后反应程度达到100%;国产M55J级碳纤维与两种航天树脂的界面剪切强度分别为74.62和62.99 MPa,均高于M55J碳纤维。

    Abstract:

    In order to strengthen the application foundation of domestic M55J carbon fiber in aerospace components, the interfacial properties of domestic M55J carbon fiber, aerospace epoxy resin and cyanate ester resin were significantly investigated, and compared with the import M55J carbon fiber. The surface morphology of carbon fiber was characterized by using scanning electron microscope and atomic force microscope. Furthermore, work of adhesion, wettability, chemical reaction characteristics and interfacial shear strength were examined by contact angle method, infrared spectroscopy and micro debonding test. The results show that there are a lot of grooves and a spot of sizing agent protuberance on the surface of domestic M55J carbon fiber. The wettability of domestic M55J carbon fiber with two kinds of aerospace resin is more superior than that of imported M55J carbon fiber, and the adhesion work between domestic M55J carbon fiber and two kinds of resin are 55.76 and 48.61 mN/m, respectively, which are higher than that of imported M55J carbon fiber. The extent of reaction of domestic M55J carbon fiber sizing agent with two kinds of aerospace resin can reach up to 100% after high-temperature curing. The interfacial shear strengths of domestic M55J carbon fiber and two kinds of aerospace resin are 74.62 and 62.99 MPa, respectively, which are higher thanc that of M55J carbon fiber.

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徐小魁,刘千立,戴晶滨,董斌,谢钟清.国产M55J级碳纤维与两种典型树脂界面性能研究[J].宇航材料工艺,2021,51(Z1):40-46.

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  • 收稿日期:2021-08-10
  • 最后修改日期:2021-09-13
  • 录用日期:2021-08-26
  • 在线发布日期: 2021-09-29
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