聚铝硅氮烷的合成、纺丝及陶瓷化性能研究
CSTR:
作者:
作者单位:

浙江理工大学材料科学与工程学院先进陶瓷材料与纤维研究所,杭州 310018

作者简介:

通讯作者:

中图分类号:

TB34

基金项目:

国家自然科学基金面上项目 (51872262)


Study on Synthesis,Spinning and Ceramic Properties of Polyaluminosilazane
Author:
Affiliation:

Institute of Advanced Ceramic Materials & Fibers,School of Materials Science and Engineering,Zhejiang Sci-Tech University,Hangzhou 310018

Fund Project:

  • 摘要
  • |
  • 图/表
  • |
  • 访问统计
  • |
  • 参考文献
  • |
  • 相似文献
  • |
  • 引证文献
  • |
  • 资源附件
  • |
  • 文章评论
    摘要:

    以不同比例的聚硅氮烷液态低聚物和乙酰丙酮铝[0.1%~1%(w)]为原料,通过热聚合反应制备了一系列聚铝硅氮烷(PASZ)先驱体。PASZ经熔融纺丝、空气预氧化处理和高温裂解后得到连续SiAlCN(O)纤维。采用FT-IR、GPC、SEM、XRD和金相显微镜等测试手段对PASZ和SiAlCN(O)纤维进行了分析表征。结果表明:PASZ的重均分子量Mw为7 191~11 275 g/mol,乙酰丙酮铝质量分数为0.2%制备的PASZ在熔融状态下表现为剪切变稀,纺丝性良好,可实现长达3 km的连续纺丝。SiAlCN(O)纤维为非晶型的含铝氮化硅纤维,直径为20~70 μm,较脆;纤维表面光滑,无裂纹、沟槽等明显缺陷。

    Abstract:

    A series of polyaluminosilazanes (PASZ) precursors were prepared by thermal polymerization with different proportion of polysilazanes liquid oligomers and aluminum acetylacetone [0.1%~1%(w)] as raw materials. The continuous SiAlCN(O) fibers were obtained via the melt spinning, air pre-oxidation treatment and high temperature cracking of PASZ. The PASZ and SiAlCN(O) fibers were characterized by FT-IR, GPC, SEM, XRD and metallographic microscopy. The results show that the mass average molecular weight of PASZ is from 7 191 to 11 275 g/mol, and prepared PASZ with 0.2% aluminum acetylacetone mass fraction shows shear thinning and excellent spinning property in molten state which could be continuously prepared up to 3 km. The SiAlCN(O) fiber is amorphous aluminum-containing silicon nitride fiber and the diameter of the fiber is about 20 to 70 μm, and the fiber surface is smooth, without obvious defects such as cracks and grooves.

    参考文献
    相似文献
    引证文献
引用本文

李海龙,陈建军.聚铝硅氮烷的合成、纺丝及陶瓷化性能研究[J].宇航材料工艺,2022,52(5):54-59.

复制
分享
文章指标
  • 点击次数:
  • 下载次数:
  • HTML阅读次数:
  • 引用次数:
历史
  • 收稿日期:2021-02-20
  • 最后修改日期:2022-08-31
  • 录用日期:2021-05-12
  • 在线发布日期: 2022-10-20
  • 出版日期:
文章二维码