石墨填料对浸渗热解-熔融浸渗方法制备的C/SiC复合材料结构和性能的影响
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作者单位:

1.中国航发商用航空发动机有限责任公司,上海 201108;2.上海商用飞机发动机工程技术研究中心,上海 201108

作者简介:

李开元(1983-),男,博士,工程师,主要研究方向:陶瓷基复合材料。联系地址:上海市闵行区莲花南路3998号(200240)Tel:+86-18621705846,E-mail:llkkyy11@126.com

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中图分类号:

TB33

基金项目:

国家重点研发计划(2016YFB1102502)


The Effects of Graphite Filler on Microstructure and Mechanical Properties of C/SiC Composites Prepared by PIP and RMI
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Affiliation:

1.AECC COMMERCIAL AIRCRAFT ENGINE CO. LTD., Shanghai 201108;2.Shanghai Center of Research for Commercial Aircraft Engine Engineering Techniques, Shanghai 201108

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    摘要:

    采用石墨树脂浆料浸渍三维针刺碳毡增强体,热解后得到C/C多孔体,并采用反应熔体浸渗法制备C/SiC复合材料。研究了石墨填料对C/C多孔体的结构以及C/SiC复合材料力学性能的影响。结果表明,石墨树脂浆料浸渍时树脂填充束间小孔形成结构致密的亚结构单元,而石墨可以有效填充胎网层等大孔隙,一次浸渍热解后碳产率有效提高。所得C/SiC复合材料包括C、SiC和Si三相,由于亚结构单元的存在,熔融Si并未渗入纤维束内部,束内碳纤维未受损伤。片层石墨的存在使碳基体/石墨和纤维结合强度提高、纤维脱粘拔出阻力增大,从而使材料强度提高;而且石墨可以使裂纹在扩展时发生偏转,从而避免了复合材料脆性断裂,使其呈现出类似金属的伪塑性断裂行为。制备出的C/SiC复合材料的弯曲断裂强度为118 MPa,最大应变可达1.0%。

    Abstract:

    High-porosity carbon fiber reinforced carbon matrix (C/C) composites, using three dimensional needle-punched carbon fiber preforms, were prepared via the impregnation and high-temperature pyrolysis of resin containing graphite filler. The C/C composites were transformed into C/SiC composites by the reactive melt infiltration method. The phase composition, microstructure and mechanical properties of C/SiC composites were investigated. The results show that the small pores among fiber bundles are efficiently filled by resin, while the large pores in the short-cut web region are filled by flake graphite particles. The yield of carbon is evidently increased after one cycle of impregnation and high-temperature pyrolysis of resin. As-prepared C/SiC composites are composed of C, SiC and a little residual Si. The internal carbon fibers are well reserved, since the Si is not impregnated into the carbon fiber bundles. The bonding strength of fiber/matrix interface and friction force during fiber pullout can be increased due to the introducing of graphite filler, so that the C/SiC composites are strengthened. The toughness of composites is also improved, since the cracks can deflect along the flake graphite. The average flexural strength of C/SiC composites reaches to 118 MPa with a maximum strain of 1.0%, and the composites exhibit pseudo-plastic fracture characteristic.

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李开元,洪智亮,郭洪宝.石墨填料对浸渗热解-熔融浸渗方法制备的C/SiC复合材料结构和性能的影响[J].宇航材料工艺,2021,51(3):60-65.

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  • 收稿日期:2020-12-19
  • 最后修改日期:2021-04-09
  • 录用日期:2021-02-23
  • 在线发布日期: 2021-06-03
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