烧蚀型防隔热/隐身多功能复合材料制备与性能
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作者单位:

1.航天材料及工艺研究所,先进功能复合材料技术重点实验室,北京 100076;2.火箭军驻北京地区第一军代室,北京 100076

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中图分类号:

TB332

基金项目:

国家自然科学基金青年基金项目(51702076);航天先进制造联合基金项目(U2037206);装备发展部预先研究项目(41422020404, 61402080108)


Preparation and Properties of Multi-Functional Composite Integrated With Heat-Shielding, Insulating and Radar-Absorbing
Author:
Affiliation:

1.Science and Technology on Advanced Functional Composite Laboratory, Aerospace Research Institute of Materials&Processing Technology, Beijing 100076;2.First Military Agency of the Rocket Force in Beijing, Beijing 100076

Fund Project:

The National Natural Science Foundation of China (General Program, Key Program, Major Research Plan)

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    摘要:

    以轻质化为前提,基于烧蚀防热借助于溶胶-凝胶技术制备出低密度防热/隔热/隐身一体化复合材料(HRC),有效地融合了烧蚀防热、高效隔热和宽频雷达隐身的功能。实验结果表明,多壁碳纳米管(MWNT)吸波剂均匀分散在杂化酚醛气凝胶骨架中,随着添加量的增加,HRC材料平均孔径减小,力学强度得到显著提升,添加5.0wt%MWNT的HRC与未添加相比压缩模量提高1.8倍。同时,MWNT的引入显著增加了HRC的雷达吸波性能,在4 ~ 18 GHz内反射率<-8 dB。地面风洞考核中,HRC表现出优异的防隔热性能,最高表面温度达到1 700 ℃左右,经过400 s烧蚀后最大背面温升(20 mm)仅为153℃,近零体积烧蚀,烧蚀后仍保持着优异的宽频雷达吸波性能。

    Abstract:

    Based on ablative mechanism and light weighting principle, heat-shielding & insulating and radar-absorbing composites (HRC), which efficiently integrated the functions of thermal protection, insulation and radar absorption in wide frequency, were prepared by sol-gel technology and resin transfer molding. SEM images showed that wave-absorbers of multi-walled nanotube (MWNT) well dispersed in the skeletons of hybrid phenolic aerogel. With increasing MWNT loading, the average pore diameter of HRC decreased and the mechanical properties were largely improved. When the MWNT loading was 5.0 wt%, compressive modulus of HRC was 1.8 times higher than that of HRC without MWNT addition. The introduction of MWNT wave-absorbers greatly improved radar-absorbing performance of HRC. The reflection loss of HRC lowered -8 dB after introducing MWNT wave-absorbers between 4 GHz and 18 GHz. In addition, HRC displayed outstanding ablative and heat-insulating properties during test of arc-jet wind tunnel. As the surface temperature of HRC reached 1700℃, temperature rise of backface with 20 mm thickness was only 153℃ and had near zero ablative recession after 400s ablating. In particularly, HRC still possessed good radar-absorbing performance in wide range of frequency after ablation in arc-jet wind tunnel.

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师建军,李弘瑜,张凌东,孔磊,冯志海.烧蚀型防隔热/隐身多功能复合材料制备与性能[J].宇航材料工艺,2021,51(6):59-64.

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  • 收稿日期:2020-06-08
  • 最后修改日期:2021-03-10
  • 录用日期:2021-03-15
  • 在线发布日期: 2022-01-13
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