MT300/802双马树脂基复合材料固化工艺及高温力学性能
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作者:
作者单位:

1.航天材料及工艺研究所,北京 100076;2.火箭军驻519厂军事代表室,北京 100076

作者简介:

李健芳,1983年出生,高级工程师,主要从事耐高温树脂设计制备及复合材料先进成型工艺研究。

通讯作者:

李桂洋,博士,高级工程师,主要从事树脂基复合材料及先进成型工艺及缺陷控制研究。E-mail:guiyang_lee@163.com.

中图分类号:

TB332

基金项目:

国家自然科学基金资助 51603058 国家自然科学基金资助(51603058)


Curing Process and High Temperature Mechanical Properties of MT300/802Bismaleimide Matrix Composites
Author:
Affiliation:

1.Aerospace Research Institute of Materials & Processing Technology, Beijing 100076;2.Military Representative Office of PLA Rocket Force in 519 Factory, Beijing 100076

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    摘要:

    采用热分析方法研究高活性802双马树脂的固化反应动力学特征,分析树脂固化度与固化温度、固化时间的关系,确定树脂固化制度150℃/1 h+180℃/2 h+200℃/4 h,制得MT300/802复合材料200℃固化T g达到325℃,而相同固化温度XU292双马树脂T g仅为234℃。进一步考察MT300/802复合材料室温、230、280及300℃的力学性能,结果表明,复合材料单向板280℃弯曲强度保持率达到了57%,300℃弯曲强度仍达到1 094 MPa,室温及高温层间剪切强度及面内剪切强度也表现出较高的性能水平,高活性802双马树脂及其复合材料固化温度相对较低而使用温度较高,能够满足航天领域耐高温主承力结构的应用要求。

    Abstract:

    Bismaleimide resin composites service as primary high temperature resistance load-carrying structure in aerospace crafts. Dynamic cure kinetics of highly reactived 802 bismaleimide resin was analyzed by differential scanning calorimetry, meanwhile its cure cycle was established as “150℃/1 h+180℃/2 h+200℃/4 h”. The T g of 802 resin is up to 325℃ cured at 200℃, significantly superior to XU292 resin (234℃) with the same curing temperature. Furthermore, MT300/802 composite mechanical properties were investigated at room temperature, 230, 280 and 300℃, respectively. Its flexural strength retention capacity is 57% at 280℃, and the 300℃ flexural strength is as high as 1 094 MPa. Meanwhile, its interlaminar and in-plane shear strength also exhibits high properties level at both room temperature and high temperature. The results indicate that MT300/802 composite has the feature of “low temperature curing and high temperature usage”, which is suitable for aerospace primary structures.

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李健芳,郭鸿俊,高杨,张东霞,李桂洋. MT300/802双马树脂基复合材料固化工艺及高温力学性能[J].宇航材料工艺,2019,49(4):34-40.

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  • 收稿日期:2018-07-09
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  • 在线发布日期: 2019-08-30
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