The Interfacial Properties of Domestic M55J Carbon Fiber and Two Typical Resins
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Affiliation:

1.Shanghai Composites Science and Technology Limited Company, Shanghai 201112;2.Shanghai Engineering Research Center of Aerospace Resin Based Composite, Shanghai 201112

Clc Number:

TB332

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    Abstract:

    In order to strengthen the application foundation of domestic M55J carbon fiber in aerospace components, the interfacial properties of domestic M55J carbon fiber, aerospace epoxy resin and cyanate ester resin were significantly investigated, and compared with the import M55J carbon fiber. The surface morphology of carbon fiber was characterized by using scanning electron microscope and atomic force microscope. Furthermore, work of adhesion, wettability, chemical reaction characteristics and interfacial shear strength were examined by contact angle method, infrared spectroscopy and micro debonding test. The results show that there are a lot of grooves and a spot of sizing agent protuberance on the surface of domestic M55J carbon fiber. The wettability of domestic M55J carbon fiber with two kinds of aerospace resin is more superior than that of imported M55J carbon fiber, and the adhesion work between domestic M55J carbon fiber and two kinds of resin are 55.76 and 48.61 mN/m, respectively, which are higher than that of imported M55J carbon fiber. The extent of reaction of domestic M55J carbon fiber sizing agent with two kinds of aerospace resin can reach up to 100% after high-temperature curing. The interfacial shear strengths of domestic M55J carbon fiber and two kinds of aerospace resin are 74.62 and 62.99 MPa, respectively, which are higher thanc that of M55J carbon fiber.

    Reference
    [1] GIBSON R F. A review of recent research on mechanics of multifunctional composite materials and structures[J]. Composite Structures, 2010, 92(12): 2793-2810.
    [2] NAITO K , YANG J M , KAGAWA Y. Tensile properties of high strength polyacrylonitrile (PAN)-based and high modulus pitch-based hybrid carbon fibers-reinforced epoxy matrix composite[J]. Journal of Materials Science, 2012, 47(6): 2743-2751.
    [3] 夏英伟,沃西源.对中国高模量碳纤维应用中工艺性能问题的分析[J].航天返回与遥感,2011,32(3):83-87.XIA Yingwei, Xiyuan WO. The operation performance analysis on high-module carbon fiber application in China[J]. Spacecraft Recovery & Remote Sensing, 2011, 32(3): 83-87.
    [4] 石文静,高峰,柴洪友.复合材料在航天器结构中的应用与展望[J].宇航材料工艺, 2019,49(4):1-6.SHI Wenjing, GAO Feng, CHAI Hongyou. Application and expectation of composite in spacecraft structure[J]. Aerospace Materials & Technology, 2019, 49(4): 1-6.
    [5] 王浩攀,高令飞,李学林.碳纤维材料在我国卫星制造领域的应用及国产化需求[J].化工新型材料,2020,48(9): 20-23.WANG Haopan,GAO Lingfei,LI Xuelin.Applications of carbon fiber composites to satellite manufacturing fields and demand for localization[J].New Chemical Materials,2020,48(9):20-23.
    [6] 张芳,许文彬,殷永霞,等.国产BHM3碳纤维在卫星结构中的应用研究[J].航天制造技术,2015(5):26-29.ZHANG Fang, XU Wenbin, YIN Yongxia, et al. Application of BHM3 carbon fiber in satellite structures[J]. Aerospace Manufacturing Technology, 2015(5): 26-29.
    [7] 李莺歌,张玉生,宫顼,等.国产高模量碳纤维制备蜂窝夹层结构件的性能评价[J].航天制造技术,2015(3):8-11,15.LI Yingge, ZHANG Yusheng, GONG Xu, et al. Performance evaluation of honeycomb sandwich structural parts manufactrued by domestic high-modulus carbon fiber[J]. Aerospace Manufacturing Technology, 2015(3): 8-11,15.
    [8] 邹豪,李伟东,彭公秋,等.高模型碳纤维的发展现状及其在航天领域的应用[J].合成纤维,2017,46(6):17-22.ZOU Hao, LI Weidong, PENG Gongqiu, et al. The development situation of high modulus carbon fiber and its applications in aerospace[J]. Synthetic Fiber in China, 2017, 46(6): 17-22.
    [9] 张月义,陈洞,丛宗杰,等.QM4055级碳纤维结构与性能分析[J].高科技纤维与应用,2019,44(4):52-58,45.ZHANG Yueyi, CHEN Dong, CONG Zongjie, et al. Structure and properties analysis of QM4055 carbon fiber[J]. Analytic Study, 2019, 44(4): 52-58,45.
    [10] 钱鑫,王雪飞,郑凯杰,等.PAN基高模量碳纤维成型过程中的结构性能关联性[J].化工进展,2019, 38(5): 2276-2283.QIAN Xin,WANG Xuefei,ZHENG Kaijie, et al. Relationship between micro-structure and macro-properties during the formation of PAN-based high modulus carbon fibers[J]. Chemical Industry and Engineering Progress, 2019, 38(5): 2276-2283.
    [11] 李兆彤,李龙,王在铎,等.碳纤维表面特征对碳/环氧复合材料界面性能的影响[J].宇航材料工艺, 2021, 51(2): 47-51.LI Zhaotong, LI Long, WANG Zaiduo, et al. Effect of carbon fiber surface characteristics on interfacial properties of carbon/epoxy composite[J]. Aerospace Materials & Technology, 2021, 51(2): 47-51.
    [12] 许昆鹏,潘书刚.表面改性高模高强碳纤维与环氧树脂界面相容性研究[J].热固性树脂,2021,36(2):43-46.XU Kunpeng,PAN Shugang. Study on interfacial compatibility of surface modified high modulus and high strength carbon fiber and epoxy resin[J]. Thermosetting Resin, 2021, 36(2): 43-46.
    [13] 李健芳,张娅婷,孙宏杰,等.国产高性能碳纤维复合材料界面性能研究[J].玻璃钢/复合材料,2013(5):28-31.LI Jianfang,ZHANG Yating,SUN Hongjie,et al. Study on interface of high performance carbon fiber composites[J]. Fiber Reinforced Plastics/Composites, 2013(5):28-31.
    [14] 冯俊.碳纤维的改性及其界面性能[J].合成树脂及塑料,2019,36(6):27-30,35.FENG Jun. Modification and interface properties of CF[J]. China Synthetic Resin and Plastics, 2019, 36(6): 27-30,35.
    [15] BEDI H S , Billing K , Agnihotri P K . Interfacial shear strength of carbon nanotubes based hybrid composites: Effect of loading rate[J]. Frattura ed Integrita Strutturale, 2019, 13(48): 571-576.
    [16] 徐永新,顾轶卓,马全胜,等.几种国产高模碳纤维特性实验分析[J].复合材料学报,2016,33(9):1905-1914.XU Yongxin,GU Yizhuo,MA Quansheng,et al. Experimental analysis of properties of several domestic high-modulus carbon fibers[J].Acta Materiae Compositae Sinica, 2016,33(9):1905-1914.
    [17] 马金瑞,李敏,张佐光.典型碳纤维的表面能差异性研究[J].航空制造技术,2014(11):73-75,79.MA Jinrui,LI Min,ZHANG Zuoguang.Study on the difference of surface free energy of typical carbon fiber[J]. Aeronautical Manufacturing Technology,2014(11):73-75,79.
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History
  • Received:August 10,2021
  • Revised:September 13,2021
  • Adopted:August 26,2021
  • Online: September 29,2021
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