POE-g-MAH 对PA66 共混体系性能的影响
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航天材料及工艺研究所

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Effect of POE-g-MAH on Properties of PA66 Blends
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    摘要:

    讨论了POE-g-MAH 含量、MAH 接枝率对PA66/ POE/ POE-g-MAH 共混物性能的影响。当POEg-
    MAH 含量为10wt% ~15wt%时,PA66/ POE-g-MAH 共混物发生脆-韧转变;随POE-g-MAH 含量增加,共混物
    的缺口冲击强度、断裂伸长率显著增大,拉伸强度、弯曲强度、弯曲模量、熔体流动速率、吸水率均明显下降。当
    POE-g-MAH 接枝率为0.05wt% ~0.2wt%时,PA66/ POE/ POE-g-MAH 共混物发生脆-韧转变;随POE-g-MAH
    接枝率增加,共混物的缺口冲击强度、断裂伸长率增大,拉伸强度、弯曲强度、弯曲模量、吸水率变化不大,熔体流
    动速率下降。SEM 照片和Molau 实验表明,POE-g-MAH 对PA66 具有显著的增容增韧效果。

    Abstract:

    The influence of POE-g-MAH content and MAH grafting rate on the blends of PA66/ POE/ POE-g-
    MAH were investigated. The brittle-ductile transition occurred when the content of POE-g-MAH changed from
    10wt% to 15wt% in the blends. With increase of the content of POE-g-MAH, the notched impact strength and the
    elongation at break of the blends increased significantly, while the tensile strength, bending strength and modulus declined,
    the melt flow rate and the water absorption decreased. While in PA66/ POE/ POE-g-MAH blends, the brittle
    -ductile transition occurred when the graft rate of POE-g-MAH changed from 0. 05wt% to 0. 2wt%. With the increase
    of graft rate of POE-g-MAH, the notched impact strength and the elongation at break of blends increased,
    while the tensile strength, bending strength and modulus, the water absorption did not change obviously, and the melt
    flow rate decreased. SEM photographs and Molau compatibility experiment showed that, POE-g-MAH had a significant
    effect both on the compatibility and toughness on PA66.

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王小黎. POE-g-MAH 对PA66 共混体系性能的影响[J].宇航材料工艺,2013,43(1).

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  • 在线发布日期: 2016-11-28
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