热处理温度对耐烧蚀酚醛树脂及其碳层力学性能的影响
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航天材料及工艺研究所,先进功能复合材料技术重点实验室,北京 100076

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TB34

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重点实验室基金(JCKY2023203-WDZC003)


The Effect of Heat Treatment Temperature on Mechanical Performance of Anti-ablation Phenolic Resin
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National Key Laboratory of Advanced Functional Composite Materials,Aerospace Research Institute of Materials &Processing Technology,Beijing 100076

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    摘要:

    针对酚醛树脂固化温度对耐烧蚀防热复合材料力学性能影响规律不清晰、树脂碳的强度随温度变化规律不清楚的问题,研究了固化温度对酚醛树脂拉伸模量和拉伸强度的影响,采用维氏显微硬度研究了热处理温度对树脂碳力学性能的影响规律。结果表明,酚醛树脂拉伸模量随固化温度升高而增大,拉伸强度随固化温度升高而趋于增大,拉伸模量最大值为5.04 GPa,拉伸强度最大值89.8 MPa,树脂的最高固化温度应不低于140 ℃;树脂碳的强度随热处理温度升高而升高,树脂碳层强度在1 100 ℃时最高,为酚醛树脂基耐烧蚀复合材料设计与制备提供了有益的指导和帮助。

    Abstract:

    In view of the unclear influence law of the curing temperature of phenolic resin on the mechanical properties of ablation-resistant thermal protection composites and the unclear strength variation law of resin carbon with temperature,the effects of curing temperature on the tensile modulus and tensile strength of phenolic resin were studied.The influence law of heat treatment temperature on the mechanical properties of resin carbon was investigated by Vickers microhardness.The results show that the tensile modulus of phenolic resin increases with the increase of curing temperature,and the tensile strength tends to increase with the increase of curing temperature.The maximum tensile modulus is 5.04 GPa,and the maximum tensile strength is 89.8 MPa.The highest curing temperature of the resin should not be lower than 140 ℃.The strength of resin carbon increases with the increase of heat treatment temperature, and the strength of resin carbon layer is the highest at 1 100 ℃.This provides beneficial guidance and assistance for the design and preparation of phenolic resin-based ablation-resistant composites.

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张犇,胡宏林,牛光明,张博雅,朱世鹏.热处理温度对耐烧蚀酚醛树脂及其碳层力学性能的影响[J].宇航材料工艺,2025,55(1):103-107.

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  • 收稿日期:2024-06-27
  • 最后修改日期:2025-02-13
  • 录用日期:2024-12-17
  • 在线发布日期: 2025-03-04
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