适用于蜂窝增强低密度材料的抗氧化涂层研究
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航天材料及工艺研究所,北京 100076

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TB332

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Study on Anti-oxidation Coating Suitable for Honeycomb-enhanced Low-density Materials
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Aerospace Research Institute of Materials & Processing Technology, Beijing 100076

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    摘要:

    研制开发出了一种适用于蜂窝增强低密度防热材料的抗氧化涂层,研究了抗氧化涂层的工艺性、表面结构、热稳定性,并采用马弗炉烧蚀实验、等离子烧蚀试验以及辐射加热试验对其烧蚀性能进行了考核。结果表明:抗氧化涂层的溶剂含量范围应为25%~75%,适用期大于165 min,涂层厚度≤300 μm。酚醛树脂STN-1的涂层热稳定性优于甲基苯基硅橡胶218-1。涂层经历800 ℃/10 min后出现了比较明显的陶瓷化现象。在1 MW/30 s和1.5 MW/30 s这两个条件下均形成了坚硬、致密的碳层。在2 000 ℃/300 s的辐射加热环境下,有涂层的蜂窝增强低密度防热材料背面温度降低了10 ℃,且碳层强度更高。

    Abstract:

    A kind of anti-oxidation coating suitable for honeycomb-enhanced low-density thermal protection material was studied.The processing property,microstructure of surface,heat resistance of the anti-oxidation coating were investigated,and the ablative property was assessed by muffle furnace ablation test,plasma ablation test and radiation heating test.The results indicates that the solvent content of anti-oxidation coating should be in range from 25% to 75%,its pot-life is greater than 165 min and its thickness is less than 300 μm.The thermal stability of the phenolic resin STN-1 coating is better than that of the methylphenyl silicon rubber 218-1.After being exposed to 800 ℃/10 min,a relatively obvious ceramicization phenomenon occurs in the coating.Under the conditions of 1 MW/30 s and 1.5 MW/30 s,a hard and dense carbon layer is formed.Under the radiation heating environment of 2 000 ℃ for 300 s,the back surface temperature of the honeycomb-reinforced low-density heat resistance material with coating is reduced by 10 ℃,and the strength of the carbon layer is higher.

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邓火英,方洲,潘艳,左小彪,代晓伟.适用于蜂窝增强低密度材料的抗氧化涂层研究[J].宇航材料工艺,2025,55(1):76-80.

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  • 收稿日期:2023-02-16
  • 最后修改日期:2025-02-13
  • 录用日期:2023-06-25
  • 在线发布日期: 2025-03-04
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