表面处理对三维浅交弯联机织复合材料界面及弯曲性能的影响
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江南大学纺织服装学院

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TS102. 1

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Effect of Surface Treatment on Interfaces and Bending Property of3D Curved Shallow鄄Crossing Linking Woven Composites
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    摘要:

    以2400 tex 无捻玻璃纤维粗纱为原料,在SGA598 型三维织机上制备出一种三维浅交弯联机织
    复合材料预制体,使用硅烷偶联剂KH-570 作为表面活性剂,采用涂抹、浸泡的方法对预制体进行表面处理以
    改善复合材料的界面性能。以环氧树脂E51 和固化剂聚醚胺WHR-H023 以质量比3 颐1 的比例组成树脂体系,
    并将经过表面处理的预制体与树脂基体以质量比1 颐1 的比例通过手糊的方式复合成型,制得三维浅交弯联机
    织复合材料。分别借助傅里叶红外光谱仪、原子力显微镜、万能材料试验机、扫描电镜等仪器来测试与验证
    KH-570 对预制体及复合材料的处理效果。结果表明,经过KH-570 处理后,预制体表面粗糙度增大、比表面
    积增加,从而使得纤维与树脂界面结合更加紧密;复合材料的弯曲性能随着KH-570 的增加而增强;复合材料
    主要破坏形式为纤维断裂,纤维在树脂中抽拔现象较少。

    Abstract:

    Curved shallow crossing linking reinforcement was prepared from glass roving of 2400 tex on a 3D
    weaving machine modeled SGA598. To improve interfacial properties between reinforcement and resin, the surface
    treatment of the reinforcement was conducted by smearing the silane coupling agent KH-570 onto the surface of the
    reinforcement and then dipping the reinforcement into the solution of KH-570. The resin matrix was composed of epoxy resin E51 and polyether amine WHR-H023 in a mass ratio of 1 1. The 3D curved shallow crossing linking woven
    composite was then made from surface treatment reinforcement and resin matrix in a mass ratio of 1  by hand lay up
    method. Fourier transform infrared spectrum(FT-IR), atomic force microscope(AFM), universal material testing ma
    chine and scanning electron microscope(SEM) were used to characterized the treatment effect of KH-570 on reinforce
    ment and the following composites. The results showed that after the treatment with surface鄄active agent KH-570, the
    surface roughness and specific surface area of fibers in the reinforcement increased which in turn led to a tighter inte
    gration between reinforcement and resin matrix; the bending properties of the 3D composites was enhanced with the
    increase of the amount of KH-570; the main failure mode of the 3D composites performed as fracture of fibers rather than fibers pulling out of the resin matrix

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冯古雨 曹海建 周洪涛 钱坤.表面处理对三维浅交弯联机织复合材料界面及弯曲性能的影响[J].宇航材料工艺,2016,46(2).

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  • 在线发布日期: 2016-11-28
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