SiC 多孔陶瓷的仿生合成
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西安建筑科技大学材料与矿资学院

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Biomimetic Synthesis of Porous SiC Ceramics
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    摘要:

    生物拟态SiC 陶瓷以硅溶胶浸渍木材模板或其碳模板结合碳热还原法制备,模板不同的显微结
    构对SiC 多孔陶瓷的仿生合成具有显著影响。结果表明:浸渍效果取决于模板的显气孔率、孔径大小及分布均
    匀性。松木的浸渍效果最好,经1 次浸渍,松木模板及其碳模板的增重率分别为66. 5wt%和76. 8wt%。经3 次
    浸渍—煅烧循环,松木的增重率为156. 8%,累积SiO2 吸收量远高于柚木和连香木。模板的显微结构、循环次
    数、煅烧温度影响陶瓷化程度,经3 次浸渍—煅烧(1 600益) 循环,由松木生成的C/ SiC 模板中残碳率仅为
    15wt%,低于由柚木或连香木生成C/ SiC 模板的1/3。1 600益煅烧4 次循环后,由松木模板生成的SiC 多孔陶
    瓷中残碳率接近零,碳细胞壁转变成SiC 多孔陶瓷细胞壁,其孔隙率为71vol%。

    Abstract:

    SiC ceramic materials with a woodlike microstructure had been fabricated by carbothermal reduction
    reactions of silica with wood or carbonized wood. The different microstructures of templates had a significant impact on
    the biomimetic synthesis of porous SiC ceramics. The infiltration efficiency is determined by the apparent porosity,
    pore size and its distribution uniformity. The infiltration efficiency for pine is best,and the weight gain percents for
    wood or carbonized wood template are respectively 66. 5% and 76. 8% after a one鄄shot infiltration. The weight gain
    percent for pine is 156. 8%, and the cumulative amount of SiO2 absorption for pine was much higher than for teak or
    katsura, after 3 cycles of infiltration鄄firing. The microstructures of templates, cycle numbers and fire temperatures in鄄
    fluenced ceramization. The residual carbon ratio for C/ SiC template from pine is only 15wt%, less than one third of
    that from teak or katsura through 3 cycles and under the firing temperature of 1 600益. The residual carbon ratio in
    the biomorphic porous SiC ceramic with the porosity of 71vol% is close to zero and the carbon cell wall is transformed
    to SiC porous ceramic cell wall from pine template through 4 cycles and under the firing temperature of 1 600益.

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蔡艳芝. SiC 多孔陶瓷的仿生合成[J].宇航材料工艺,2013,43(2).

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  • 在线发布日期: 2016-11-28
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