微量Al 掺杂对2D C/ SiC 性能的影响
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西北工业大学超高温结构复合材料重点实验室

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Effects of Adding a Small Amount of Al on Properties of 2D C/ SiC
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    摘要:

    以二维编织碳纤维碳布为预制体,采用聚铝碳硅烷(PACS)为聚合物前驱体,应用化学气相渗透
    (CVI) 结合聚合物浸渗-裂解(PIP)工艺制备微量Al 掺杂2D C/ SiC 复合材料。研究微量Al 掺杂对C/ SiC 微
    观结构、力学、热膨胀和氧-乙炔焰烧蚀性能的影响。结果表明:掺杂微量Al 未改变C/ SiC 的微观结构和热膨
    胀性能,也未降低其韧性和强度;但微量Al 掺杂提高了C/ SiC 的抗烧蚀性能,含微量Al 的SiC 氧化形成微量
    Al 熔于SiO2的固熔体,微量Al 提高了SiO2的黏度和致密度,减小SiO2挥发,较未掺杂Al 的C/ SiC 相比,线烧蚀
    率降低了26%。

    Abstract:

    Two鄄dimensional(2D) C/ SiC composites were fabricated by chemical vapor infiltration(CVI) com鄄
    bined with polymer impregnation and pyrolysis( PIP) using polyaluminocarbosilane( PACS) as precursor. Properties
    including microstructure,mechanical properties and thermal expansion of the composites were investigated. The abla鄄
    tion properties of C/ SiC composites were investigated by the oxyacetylene torch flame. The results show that adding a
    small amount of Al has little effect on microstructure, coefficient of thermal expansion( CTE),flexural strength and
    toughness of composites. However,the addition of a small amount of Al into C/ SiC composite effectively enhances its
    ablation resistance. SiC reacts with oxygen to form a silica film,which causes Al melt into silica. Al doping can not on鄄
    ly increase the viscosity of silica,but also reduce the activity of silica. Compare with the no addition of Al into C/ SiC
    composites,the linear ablation rate decreased by 26%.

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孙静.微量Al 掺杂对2D C/ SiC 性能的影响[J].宇航材料工艺,2012,42(3).

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  • 在线发布日期: 2016-11-28
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