集中交联硅橡胶硫化体系及其工艺
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西南科技大学材料学院

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Curing System and Process of Silicone Rubber With Concentrative Crosslinker
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    摘要:

    采用动态热机械分析仪RSA3 代替硫化仪来测试硅橡胶的硫化特性,使用多乙烯基硅油(C 胶)
    作为集中交联剂,分别选择DCP、BPO 及两者并用硫化体系作为集中交联硅橡胶体系的硫化剂,研究了不同硫
    化剂对集中交联硅橡胶硫化曲线的影响,分析了硅橡胶在不同硫化体系下发生交联反应的差异,讨论了硅橡胶
    在不同温度下的硫化反应速率。研究结果表明:对于集中交联体系的硅橡胶,BPO 硫化效果不好,DCP 能有效
    硫化,并用硫化体系的硫化效果最好,且可以在不影响其硫化反应速率的同时使硅橡胶实现高低温分段硫化。

    Abstract:

    The curing characteristics of unvulcanized filled silicone rubber were investigated by a Dynamic Me chanical Thermal Analyzer (DMTA) called RSA3 instead of curemeters. The influence of curing agent type on the cu ring characteristics of silicone rubber when choosing polyvinylsilicone oil, namely C gum, as concentrative crosslinker were studied. And the differences of crosslink reactions of rubber with three different curing agents were also dis cussed. The results show that benzoyl peroxide (BPO) can爷t well cure silicone rubber with C gum. While the di cumyl peroxide (DCP), one vinyl鄄specific curing agent, can well cure silicone rubber with C gum. The best cure
    effect in the presence of concentrative crosslinking of silicone rubber of this research is a combination of DCP and BPO. The silicone rubber cured with the combination of BPO and DCP have high modulus, and the rubber can be cured by two cure stages of low and high cure temperature without cure reactions rate decreasing.

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李艳 芦艾 杨海波.集中交联硅橡胶硫化体系及其工艺[J].宇航材料工艺,2011,41(4).

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  • 在线发布日期: 2016-11-28
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